Preparation of 1,5-diaryl-3-(arylamino)-1H-pyrrol- 2(5H)-one derivatives using 1-methylpiperidinium hydrogen sulfate as an efficient catalyst
Authors
Abstract:
A highly efficient and environmentally friendly synthesis of various 1,5-diaryl-3-(arylamino)-1H-pyrrol-2(5H)-ones catalyzed by 1-methylpiperidinium hydrogen sulfate via one-pot cyclo-condensation reaction ofaldehydes, amines and ethyl 2-oxopropanoate under ambient conditions has been explored. The presentmethodology offers several advantages such as good yields, simple procedure, shorter reaction times andmilder conditions and the products were purified without resorting to chromatography.
similar resources
preparation of 1,5-diaryl-3-(arylamino)-1h-pyrrol- 2(5h)-one derivatives using 1-methylpiperidinium hydrogen sulfate as an efficient catalyst
a highly efficient and environmentally friendly synthesis of various 1,5-diaryl-3-(arylamino)-1h-pyrrol-2(5h)-ones catalyzed by 1-methylpiperidinium hydrogen sulfate via one-pot cyclo-condensation reaction ofaldehydes, amines and ethyl 2-oxopropanoate under ambient conditions has been explored. the presentmethodology offers several advantages such as good yields, simple procedure, shorter react...
full textThe preparation of quinoxaline and 2,3-dihydropyrazine derivatives using selectfluor as an efficient and reusable catalyst
Selectfluor [1-(chloro methyl) -4-flouro -1,4-di azonia bicyclo[2,2,2] octane bis (tetraflouro-borate)] catalyzed the preparation of quinoxaline and 2,3-dihydo pyrazine derivatives through one -pot condensation of 1,2-di amines with 1,2-di carbonyls in solvent and under solvent- free conditions. This catalyst is commercially available, inexpensive, reusable, stable to air and moisture, and rela...
full textAn efficient facile and one-pot synthesis of 2-arylsubstituted benzimidazole derivatives using 1-methyl-3-(2-oxyethyl)-1H-imidazol-3-ium-borate sulfonic acid as a recyclable and highly efficient ionic liquid catalyst at green condition
1-Methyl-3-(2-oxyethyl)-1H-Imidazol-3-ium-Borate Sulfonic Acid ([MOEI]-BSA) was easily prepared and used as a new and highly efficient solid acid catalyst for the synthesis of benzimidazole derivatives with high isolated yields. Various substituted benzimidazoles were synthesized by a combination of o-phenylenediamines and aldehydes in the presence of [MOEI]-BSA with excellent yields in water a...
full textMontmorillonite modified as an efficient and environment friendly catalyst for one- pot synthesis of 3, 4-dihydropyrimidine-2(1H) ones
Montmorillonite modified is an efficient environmental friendly catalyst under one-pot-three-component synthesis of 3,4-dihydropyrimidine-2(1H) ones. The preparation was performed with an aldehyde, 1,3-dicarbonyl compounds, urea or thiourea under solvent-free conditions. In comparison with the other methods of Biginelli reaction, this new method has short reaction time inexpensive catalyst and ...
full textchemoselective preparation of acylals using 1-methyl-3-(2-(sulfooxy)ethyl)-1h-imidazol-3-ium chloride as an efficient and reusable catalyst
an efficient and chemoselective procedure for the preparation of 1, 1-diacatates (acylals) from various aldehydes with acetic anhydride in the presence of brønsted acidic ionic liquid [msei]cl as a reusable catalytic system under solvent-free condition at room temperature and short periods of times with excellent yields will be described. the catalyst was easily separated in simple work-up and ...
full textSynthesis of 2-aryl-1H-benzo[d]imidazole derivatives using nano montmorillonite clay as an efficient catalyst
Benzimidazoles are among the most important nitrogen-containing heterocyclic compounds that have many pharmaceutical applications; including, antitumor, anticancer, anticorrosive, antibacterial, irritant and enzymatic interceptors. In this research, the synthesis of benzimidazoles using o-phenylenediamine and aldehyde derivatives in the presence of the nano montemurillonite in solvent-...
full textMy Resources
Journal title
volume 5 issue 2
pages 65- 71
publication date 2012-06-20
By following a journal you will be notified via email when a new issue of this journal is published.
Hosted on Doprax cloud platform doprax.com
copyright © 2015-2023