One-pot Synthesis of Pyrano[2,3-d]Pyrimidines using Nanocellulose-SbCl5 as a Highly Efficient and Bio-based Catalyst

Authors

Bahareh Sadeghi Department of Chemistry, Yazd Branch, Islamic Azad University, Yazd, Iran

Marziyeh Rouhi Department of Chemistry, Yazd Branch, Islamic Azad University, Yazd, Iran

Mohammad Hosain Moslemin Department of Chemistry, Yazd Branch, Islamic Azad University, Yazd, Iran

Saleheh Zavar Department of Chemistry, Payame Noor University, Tehran, Iran

Abstract:

The reaction of nano-cellulose and antimony pentachloridein dichloromethane gave nano-cellulose-SbCl5. Also nano-cellulose-SbCl5 has beencharacterized by energy dispersive X-ray spectroscopy(EDX), scanning electron microscopy (SEM)and Fourier transform infrared spectroscopy(FTIR).Nano-cellulose-SbCl5has been applied as a nano-catalyst for synthesis of pyrano[2,3-d]pyrimidines from the simple one-pot reaction between aryl aldehydes,barbituric acid orthiobarbituric acid and malononitril.Cleanliness, simple methodology, short time, and excellentyields of products are some advantages of this method.

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