Internal strain on the bond length and rate of hydrolysis in cyclic amides

Authors

  • Javad Azizian Department of Chemistry, Islamic azad university, Science and research branch, Tehran, Iran
  • Mahdieh Entezari Department of Chemistry, Islamic azad university, mahshahr branch, Mahshahr, Iran
  • Shahab Zomorod bakhsh Department of Chemistry, Islamic azad university, mahshahr branch, Mahshahr, Iran
Abstract:

The internal strain in cyclic amides are explained as a factor of resonance that are effected on the bond length C-N and are a major factor of rates of hydrolysis. The cyclic amides in this study are optimized by Gaussian program and the bond length of C-N in the rings are studied by HF/6-31G*.

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Theoretical study of the effect of internal strain on the bond length and rate of hydrolysis in cyclic amides

The internal strain in cyclic amides are explained as a factor of resonance that are effected on the bond length C-N  and are a major factor of rates of hydrolysis. The cyclic amides in this study are optimized by Gaussian program and the bond length of C-N in the rings are studied by HF/6-31G*.  

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Theoretical study of the effect of internal strain on the bond length and rate of hydrolysis in cyclic amides

The internal strain in cyclic amides are explained as a factor of resonance that are effected on the bond length C-N  and are a major factor of rates of hydrolysis. The cyclic amides in this study are optimized by Gaussian program and the bond length of C-N in the rings are studied by HF/6-31G*.

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Journal title

volume 5  issue 1

pages  8- 12

publication date 2015-04-01

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