[Fe(III)(Salen)Cl] Complex as a Catalyst for the Synthesis of 1, 8-Dioxo-Octahydroxanthene Derivatives
Authors
Abstract:
1, 8-Dioxo-octahydroxanthene derivatives have efficiently been synthesized from dimedone and aromatic aldehydes using [Fe(III)(salen)Cl] complex as an efficient and homogeneous catalyst in molten tetrabutyl ammonium bromide. This methodology offers several advantages, such as good yields, short reaction times, simple procedure, and mild conditions.
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چکیده ندارد.
Clean synthesis of 1,8-dioxo-octahydroxanthene derivatives using NBS as an efficient and almost neutral catalyst in aqueous media
An efficient one-pot condensation for the synthesis of 1,8-dioxo-octahydroxanthene is achieved through a condensation of aryl aldehydes and 5,5-dimethyl-1,3-cyclohexandione in the presence of NBS. This method enjoys several advantages such as low cost, simple work up procedure and safe reaction condition. In addition, water was chosen as a green solvent.
full textIntroduction of two efficient catalysts for the synthesis of 1,8-dioxo-octahydroxanthene derivatives in the absence of solvent
1,3-Dibromo-5,5-dimethylhydantoin (DBH) and benzyltriphenylphosphoniumtribromide (BTPTB) were used as efficient catalysts for the promotion of the synthesis of 1,8-dioxo-octahydroxanthene derivatives (DOXOs) via a one-pot three component condensation of aldehydes and cyclic 1,3-dicarbonyl compounds in the absence of solvent.
full textIntroduction of two efficient catalysts for the synthesis of 1,8-dioxo-octahydroxanthene derivatives in the absence of solvent
1,3-Dibromo-5,5-dimethylhydantoin (DBH) and benzyltriphenylphosphoniumtribromide (BTPTB) were used as efficient catalysts for the promotion of the synthesis of 1,8-dioxo-octahydroxanthene derivatives (DOXOs) via a one-pot three component condensation of aldehydes and cyclic 1,3-dicarbonyl compounds in the absence of solvent.
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Journal title
volume 24 issue 2
pages 123- 127
publication date 2013-06-01
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