Efficient synthesis of β-hydroxy thiocyanates from epoxides and ammonium thiocyanate using 1,4-bis(triphenylphosphonium)-2-butene dichloride as a new catalyst

Authors

  • Maryam Gorjizadeh Department of Chemistry, Shoushtar Branch, Islamic Azad University, Shoushtar Iran
  • Mohammad Azarkish Department of Chemistry, Shoushtar Branch, Islamic Azad University, Shoushtar Iran
  • Mozhgan Afshari Department of Chemistry, Shoushtar Branch, Islamic Azad University, Shoushtar Iran
Abstract:

1,4-bis(triphenylphosphonium)-2-butene dichloride was developed as a new phase transfer catalyst. This quaternized phosphonium salt catalyzed the regioselective ring opening of epoxides by thiocyanate ion to give β-hydroxy thiocyanates in high yields under mild conditions.

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Journal title

volume 1  issue 3

pages  12- 16

publication date 2011-05-01

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