In this paper, the effect of nanocatalytic metal-organic framework based on copper metal and bis-tetrazolamine (CuBTA) ligand functionalized with cobalt (II) oxide nanoparticles on the thermal decomposition behavior of ammonium perchlorate (AP), using differential survey calorimetry (DSC) has been reviewed. First, the metal-organic framework (CuBTA) was synthesized from the raw materials of copper chloride and bistetrazole amine using the solvothermal method and with the help of .... Then, using cobalt (II) nitrate and co-precipitation method, the desired metal-organic framework was functionalized with cobalt (II) oxide nanoparticles. Fuzzy studies were performed with X-ray diffraction pattern (XRD) apparatus, as well as formation investigations using Fourier transform infrared spectroscopy (FT-IR). The results of thermal decomposition of ammonium perchlorate in the presence of metal-organic framework (CuBTA) and nanoparticle functionalized framework showed that 5% by weight of the catalyst, the thermal decomposition temperature of ammonium perchlorate was 34.1 °C and 91.1 °C. Reduced for the metal-organic framework and the metal-organic framework functionalized by nanoparticles, respectively. The combustion enthalpies of 1570 J.g-1 and 1375 J.g-1  were obtained in the same way.