B-podands as efficient catalysts for the ring opening of epoxides in water: A versatile and atom economical method for the synthesis of vicinal azidoalcohols

Authors

Ali Kiasat Department of Chemistry, College of Science, Shahid Chamran University, Ahvaz 61357-4-3169, I.R. Iran.

Fakhri Ataeian Department of Chemistry, College of Science, Shahid Chamran University, Ahvaz 61357-4-3169, I.R. Iran.

Mehdi Fallah-Mehrjardi Department of Marine Chemistry, Khorramshahr University of Marine Science and Technology, Khorramshahr 669, I.R. Iran.

Abstract:

For the first time B-podands have been studied as an efficient and powerful catalysts in the ring opening of epoxides with azide anion in water. The reaction afforded the corresponding 1,2-azidoalcohols with high regioselectivity under mild reaction conditions and in a highly atom economic fashion.

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b-podands as efficient catalysts for the ring opening of epoxides in water: a versatile and atom economical method for the synthesis of vicinal azidoalcohols

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