Application of PVPP-OXA as an efficient catalyst for the synthesis of mono and bulky 1,8-dioxooctahydroxanthenes

Authors

  • Masoud Mokhtary Department of Chemistry, Rasht Branch, Islamic Azad University, Rasht, Iran
  • Reza Dezhanga Department of Chemistry, Rasht Branch, Islamic Azad University, Rasht, Iran
Abstract:

An efficient method for the synthesis of mono and bulky 1,8-dioxooctahydroxanthenes was developed by the reaction of dimedone or 1,3-cyclohexadione and aldehydes or some bisaldehydes in the presence of polyvinylpolypyrrolidone supported oxalic acid (PVPP-OXA) as a new polymeric catalyst in ethanol at room temperature. Polyvinylpolypyrrolidone supported oxalic acid was characterized by FT-IR, and TGA analysis. Clean methodologies, simple preparation of the catalyst, high yields, environment-friendly and reusable catalyst are some advantages of this work.    

Upgrade to premium to download articles

Sign up to access the full text

Already have an account?login

similar resources

Polyvinylpolypyrrolidone supported antimony(III) chloride (PVPP-SbCl3): An efficient catalyst for the synthesis of chromenylphenylpropanones

An efficient synthesis of chromenylphenylpropanone derivatives as warfarine-like analogues was developed by the Michael addition of 4-hydroxycoumarin to α,β-unsaturated compounds in the presence of polyvinylpolypyrrolidone supported antimony(III) chloride (PVPP-SbCl3) as a new polymeric Lewis acid catalyst in chloroform at reflux conditions without formation of 2,4-...

full text

Polyvinylpolypyrrolidone supported antimony(III) chloride (PVPP-SbCl3): An efficient catalyst for the synthesis of chromenylphenylpropanones

An efficient synthesis of chromenylphenylpropanone derivatives as warfarine-like analogues was developed by the Michael addition of 4-hydroxycoumarin to α,β-unsaturated compounds in the presence of polyvinylpolypyrrolidone supported antimony(III) chloride (PVPP-SbCl3) as a new polymeric Lewis acid catalyst in chloroform at reflux conditions without formation of 2,4-...

full text

an application of fuzzy logic for car insurance underwriting

در ایران بیمه خودرو سهم بزرگی در صنعت بیمه دارد. تعیین حق بیمه مناسب و عادلانه نیازمند طبقه بندی خریداران بیمه نامه براساس خطرات احتمالی آنها است. عوامل ریسکی فراوانی می تواند بر این قیمت گذاری تاثیر بگذارد. طبقه بندی و تعیین میزان تاثیر گذاری هر عامل ریسکی بر قیمت گذاری بیمه خودرو پیچیدگی خاصی دارد. در این پایان نامه سعی در ارائه راهی جدید برای طبقه بندی عوامل ریسکی با استفاده از اصول و روش ها...

Preparation and application of HMCM-22 zeolite as an efficient solid acid catalyst for the synthesis of acetals

HMCM-22 with a Si:Al molar ratio of 15:1 has been shown to effectively catalyze the synthesis of acetals with 100% selectivity by the reaction of aldehydes with methanol under reflux conditions. Platelet HMCM-22 particles were prepared by the static strategy and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), BET tech...

full text

Preparation and application of HMCM-22 zeolite as an efficient solid acid catalyst for the synthesis of acetals

HMCM-22 with a Si:Al molar ratio of 15:1 has been shown to effectively catalyze the synthesis of acetals with 100% selectivity by the reaction of aldehydes with methanol under reflux conditions. Platelet HMCM-22 particles were prepared by the static strategy and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), BET tech...

full text

My Resources

Save resource for easier access later

Save to my library Already added to my library

{@ msg_add @}


Journal title

volume 13  issue 4

pages  18- 27

publication date 2019-09-01

By following a journal you will be notified via email when a new issue of this journal is published.

Hosted on Doprax cloud platform doprax.com

copyright © 2015-2023