A KINETIC STUDY OF THE DECOMPOSITION OF PYRIDINE CHROMIUM (VI) PEROXIDE WITH ALCOHOLS
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Abstract:
A kinetic study of the decomposition of pyridine chromium peroxide with methanol, ethanol, propanol and isopropanol has been made over the temperature range 25 to 40°C. It is found that the ligand exchange stage is the rate determining step in the oxidation process. The activation parameters E , ?H‡ and ?S‡ for the reactions are determined. It is believed that the peroxide linkage is primarily responseble for the oxidation process
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full textkinetic study of the reaction of 2,2’-bipyridyl chromium peroxide with alcohols
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Journal title
volume 4 issue 4
pages -
publication date 1993-12-01
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