4-Chloro-3,5-dioxaphosphacyclohepta[2,1-;3,4-']dinaphthalene (BINOL-PCl) as a Bulky and Efficient Reagent for the Transformation of Symmetric and Asymmetric Benzoins to Corresponding Benziles

Authors

  • Bakhshali Massoumi Department of Chemistry, Tabriz Payam-e-noor University, Tabriz, Iran
  • Mahnaz Saraei Department of Chemistry, Tabriz Payam-e-noor University, Tabriz, Iran
  • Maryam Sarbazi Department of Chemistry, Tabriz Payam-e-noor University, Tabriz, Iran
Abstract:

4-Chloro-3,5-dioxaphosphacyclohepta[2,1-;3,4-']dinaphthalene (BINOL-PCl) was found to be an efficient, bulky and selective reagent for the transformation of symmetric and asymmetric benzoins to the corresponding benziles at 0 °C to room temperature under nitrogen atmosphere in good yield.

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Journal title

volume 4  issue 1

pages  51- 57

publication date 2011-03-20

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