Polymer aggregation correlated transition from Schottky-junction to bulk heterojunction organic solar cells

Improvement of light harvesting by inserting an optical spacer (ZnO) in polymer bulk heterojunction solar cells: A theoretical and experimental study

By introducing a thin ZnO layer as an optical spacer, we have demonstrated that inserting this layer between an active layer and a reflective electrode results in a re-distribution of the optical electric field inside bulk heterojunction solar cells. A theoretical analysis by optical modeling showed that the thin ZnO layer could shift the position of the maximum of the electric field into the a...

Junction formation and current transport mechanisms in hybrid n-Si/PEDOT:PSS solar cells

UNLABELLED We investigated hybrid inorganic-organic solar cells combining monocrystalline n-type silicon (n-Si) and a highly conductive polymer poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonate) ( PEDOT PSS). The build-in potential, photo- and dark saturation current at this hybrid interface are monitored for varying n-Si doping concentrations. We corroborate that a high build-in potent...

High-performance multiple-donor bulk heterojunction solar cells

Broadening the absorption bandwidth of polymer solar cells by incorporating multiple absorber donors into the bulk-heterojunction active layer is an attractive means of resolving the narrow absorption of organic semiconductors. However, this leads to a much more complicated system, and previous efforts have met with only limited success. Here, several dual-donor and multi-donor bulk-heterojunct...

Studies of Charge Transport and Energy Level in Solar Cells Based on Polymer/Fullerene Bulk Heterojunction

Temperature-dependent Schottky barrier in high-performance organic solar cells

Organic solar cells (OSCs) have attracted great attention in the past 30 years, and the power conversion efficiency (PCE) now reaches around 10%, largely owning to the rapid material developments. Meanwhile with the progress in the device performance, more and more interests are turning to understanding the fundamental physics inside the OSCs. In the conventional bulk-heterojunction architectur...