Characterization of a high-spin non-heme {FeNO}(8) complex: implications for the reactivity of iron nitroxyl species in biology.
نویسندگان
چکیده
Stable but able: Chemical and electrochemical reduction of a five-coordinate high-spin non-heme {FeNO}(7) complex (see structure: N blue, Fe orange, and O red) generated the first stable high-spin (S=1) non-heme {FeNO}(8) model complex. The finding that the reduction is metal-centered and causes a decrease in FeNO covalency indicates that in biological systems, reduction activates stable non-heme FeNO units for further transformations.
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 52 47 شماره
صفحات -
تاریخ انتشار 2013