μ4-Orthothiocarbonato-tetrakis[tricarbonyliron(I)](2 Fe—Fe)
نویسندگان
چکیده
The fused bis-butterfly-shaped title compound, [Fe(4)(CS(4))(CO)(12)], possesses an orthothio-carbonate (CS(4) (4-)) ligand that acts as a bridge between two Fe(2)(CO)(6) units. A short intra-molecular S⋯S contact [2.6984 (8) and 2.6977 (8) Å] occurs in each S(2)Fe(2)(CO)(6) fragment.
منابع مشابه
Decacarbonyl[μ4-(ethane-1,2-diyldinitrilo)tetrakis(methanethiolato)]bis(triphenylphosphane)tetrairon(2 Fe—Fe)
In the title compound, [Fe(4)(C(6)H(12)N(2)S(4))(C(18)H(15)P)(2)(CO)(10)], the unit cell contains one mol-ecule, which exhibits a crystallographically imposed center of symmetry. The independent Fe(2)S(2) fragment [Fe-Fe = 2.527 (1) Å] is in a butterfly conformation, and each Fe atom displays a pseudo-square-pyramidal coordination geometry. The phosphane group occupies an apical position [Fe-P ...
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