Three new resin glycosides and a new tetrahydropyran derivative from the seeds of Quamoclit pennata.
نویسندگان
چکیده
Three new resin glycosides, quamoclins V (1), VI (2), and VII (3) and a new tetrahydropyran derivative, quamopyran (4), were isolated from the seeds of Quamoclit pennata BOJER (Convolvulaceae). The chemical structures of these compounds were determined primarily on the basis of spectroscopic data. The carboxyl group of the aglycone, 11S-convolvulinolic acid, of 1 and 2 was linked intermoleculary with a hydroxy group of the sugar moiety to form a macrocyclic ester structure, as in already known jalapins, and 3 was an acylated glycosidic acid methyl ester. All of the sugar moieties of 1-3 were acylated by one 2S-methylbutyric acid. Compound 4 was a diketone having a tetrahydropyran ring.
منابع مشابه
Two new glycosidic acids, quamoclinic acids G and H, of the resin glycosides (Convolvulin) from the seeds of Quamoclit pennata.
Two new glycosidic acids, quamoclinic acids G and H, were isolated from the glycosidic acid fraction afforded by alkaline hydrolysis of the ether-insoluble resin glycoside (convolvulin) fraction from the seeds of Quamoclit pennata BOJER. Both compounds are the first examples of bisdesmosides of glycosidic acid having the sugar linkages at C-3 of 3,11-dihydroxytetradecanoic acid (ipurolic acid) ...
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ورودعنوان ژورنال:
- Chemical & pharmaceutical bulletin
دوره 60 8 شماره
صفحات -
تاریخ انتشار 2012