Illustrating consistency of different experimental approaches to probe the buried polymer/metal interface using sum frequency generation vibrational spectroscopy.
نویسندگان
چکیده
In this paper, we demonstrate our ability to directly probe the molecular structures of the buried polymer/metal interface using sum frequency generation (SFG) vibrational spectroscopy. Spectroscopic data from different experimental approaches were compared and analyzed to deduce the molecular ordering information at a buried polymer/metal interface, i.e. the poly(n-butyl methylacrylate) (PBMA)/silver (Ag) interface. Solid spectroscopic evidence suggested that we successfully detected the molecular vibrational signals generated from the buried PBMA/Ag interface. It was found that the side butyl methyl groups at the PBMA/Ag interface are polar-ordered and have different orientational ordering from those at the PBMA surface in air. We believe that this study will provide a useful experimental and analytical framework for the SFG spectroscopy to probe the buried polymer/metal interfaces in the future.
منابع مشابه
Mini Review Understanding surfaces and buried interfaces of polymer materials at the molecular level using sum frequency generation vibrational spectroscopy
This paper reviews recent progress in the studies on polymer surfaces/interfaces using sum frequency generation (SFG) vibrational spectroscopy. SFG theory, technique, and some experimental details have been presented. The review is focused on the SFG studies on buried interfaces involving polymer materials, such as polymer–water interfaces and polymer–polymer interfaces. Molecular interactions ...
متن کاملPlasma treatment effect on polymer buried interfacial structure and property.
Adhesion is important in many industrial applications including those in the microelectronics industry. Flip-chip assemblies commonly utilize epoxy underfills to promote reliability and the buried interfacial structure of underfills is crucial to device lifetime. Poor adhesion at this interface can cause premature device failure. One method to increase adhesion strength is to plasma treat the s...
متن کاملMolecular Level Studies of Polymer Behaviors at the Water Interface Using Sum Frequency Generation Vibrational Spectroscopy
Industrial plastics, biomedical polymers and numerous other polymeric systems are contacted with water for everyday functions and after disposal. Probing the interfacial molecular interactions between widely used polymers and water yields valuable information that can be extrapolated to macroscopic polymer/water interfacial behaviors so scientists can better understand polymer bio-compatibility...
متن کاملAdsorption of 4-picoline and piperidine to the hydrated SiO2 surface: probing the surface acidity with vibrational sum frequency generation spectroscopy.
Vapor adsorption is an important process influencing the migration and the fate of many organic pollutants in the environment. In this study, vibrational sum frequency generation (SFG) spectroscopy was used to study the adsorption of two surface acidity probe molecules, 4-picoline (pKa = 5.94) and piperidine (pKa = 11.24), onto the amorphous SiO2 surface. The adsorption of 4-picoline onto the s...
متن کاملThe thermal reorganization of DNA immobilized at the silica/buffer interface: a vibrational sum frequency generation investigation.
We have monitored the interactions of DNA strands immobilized on silica at the buried solid/liquid interface using vibrational sum frequency generation. We find that the nucleobases exhibit net order even prior to hybridization for immobilized single strands. Moreover, varying the temperature of the hybridized samples leads to spectral changes from the thymine nucleobases that are consistent wi...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Soft matter
دوره 10 29 شماره
صفحات -
تاریخ انتشار 2014