2,8-Dichloro-6H,12H-5,11-ethanodibenzo[b,f][1,5]diazocine
نویسندگان
چکیده
In the mol-ecule of the title compound, C(16)H(14)Cl(2)N(2), the ethano-strapped 2,8-dichloro analogue of Tröger's base, the dihedral angle between the two benzene rings is 87.01 (3)°.
منابع مشابه
2,8-Dibromo-4,10-dichloro-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine
The title compound, C(15)H(10)Br(2)Cl(2)N(2), a 2,8-dibromo-4,10-dichloro Tröger's base analogue derived from 4-bromo-2-chloro-aniline, has a dihedral angle of 110.9 (10)° between the two aryl rings, the largest yet measured for a simple dibenzo analogue.
متن کامل6H,12H-5,11-Ethanodibenzo[b,f][1,5]diazocine
In the mol-ecule of the title compound, C(16)H(16)N(2), the ethano-strapped analogue of unsubstituted Tröger's base, the dihedral angle between the two benzene rings is 75.85 (4)°, the smallest angle measured for an ethano-strapped analogue.
متن کامل2,8-Dimesitylboranyl-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine
In the title compound, C(51)H(56)B(2)N(2), a substituted Tröger's base, the dihedral angle between the two benzene rings constituting the Tröger's base framework is 104.42 (6)°. The crystal structure is stabilized by C-H⋯π and weak C-H⋯N inter-actions.
متن کاملDimethyl 6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine-2,8-diacetate
The asymmetric unit of the title compound, C(21)H(22)N(2)O(4), a Tröger's base analogue derived from methyl 4-amino-phenyl-acetate, contains two crystallographically independent mol-ecules with dihedral angles of 88.44 (5) and 88.68 (6)° between the two benzene rings.
متن کاملRacemic 1,2,3,4,7,8,9,10-octafluoro-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine: an octafluorinated analogue of Tröger’s base
The title compound, C(15)H(6)F(8)N(2), possesses a non-crystal-lographic twofold axis. The dihedral angle between the two benzene rings is 98.4 (2)°. The crystal structure involves intermolecular C-H⋯F hydrogen bonds.
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