Palladium-catalyzed asymmetric hydrogenation of functionalized ketones.
نویسندگان
چکیده
[reaction: see text]. A novel catalytic system for asymmetric hydrogenation of functionalized ketones has been developed using a Pd/bisphosphine complex as the catalyst in 2,2,2-trifluoroethanol. The reaction exhibits high enantioselectivity, and up to 92.2% ee was obtained.
منابع مشابه
Asymmetric transfer hydrogenation of ketones catalyzed by rhodium complexes containing amino acid triazole ligands.
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عنوان ژورنال:
- Organic letters
دوره 7 15 شماره
صفحات -
تاریخ انتشار 2005