"Inverse-electron-demand" ligand substitution in palladium(0)-olefin complexes.
نویسندگان
چکیده
Ligand substitution reactions are ubiquitous in transition-metal chemistry and catalysis. Investigation of ligand substitution reactions for a series of electron-rich palladium(0)-olefin complexes, (bathocuproine)Pd(nitrostyrene) reveals an unprecedented mechanism in which the metal serves as the nucleophilic partner in an "associative" substitution pathway.
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 125 1 شماره
صفحات -
تاریخ انتشار 2003