Capture and metathesis-based release of potassium salts by a multitopic ion receptor.

نویسندگان

  • Sung Kuk Kim
  • Benjamin P Hay
  • Jong Seung Kim
  • Bruce A Moyer
  • Jonathan L Sessler
چکیده

The multitopic ion-pair receptor 2 is able to recognize and extract various cesium and potassium salts via three different ion recognition modes. Furthermore, it is capable of extracting and then releasing KNO(3)via ion-pair metathesis with CsClO(4), allowing KNO(3) recovery.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Selective solid-liquid extraction of lithium halide salts using a ditopic macrobicyclic receptor.

A ditopic salt receptor that is known to bind and extract solid NaCl, KCl, NaBr, and KBr into organic solution as their contact ion pairs is now shown by NMR and X-ray crystallography to bind and extract solid LiCl and LiBr as water-separated ion pairs. The receptor can transport these salts from an aqueous phase through a liquid organic membrane with a cation selectivity of K+ > Na+ > Li+. How...

متن کامل

سینتیک رهاسازی پتاسیم از فلدسپار پتاسیم در مقایسه با موسکویت تحت تأثیر عصاره گیرهای مختلف

In Iran, no research has yet been performed on potassium release from feldspar in comparison with that from muscovite. The objective of this research was to compare potassium release kinetics of these minerals as influenced by organic and inorganic extractants using successive extraction method. The experiment was carried out in a completely randomized design with a factorial combination. Treat...

متن کامل

Sulfonium-based Ionic Liquids Incorporating the Allyl Functionality

A series of sulfonium halides bearing allyl groups have been prepared and characterized. Anion metathesis with Li[Tf2N] and Ag[N(CN)2] resulted in sulfonium-based ionic liquids which exhibit low viscosities at room temperature. The solid state structure of one of the halide salts was determined by single crystal X-ray diffraction.

متن کامل

Improving Thermal Stability of Starch in Formate Fluids for Drilling High Temperature Shales

Starch is one of the most widely used biopolymers in water based drilling fluids to control fluid loss. The thermal stability of starch in common drilling fluids is low (93 °C). In this study, the thermal stability of starch has been evaluated in sodium/potassium formate and potassium chloride fluids. Samples of mud were prepared by formate salts (sodium and potassium) and potassium chloride wi...

متن کامل

Alkoxy substituted halogenated closo-dodecaborates as anions for ionic liquids.

Halogenated and alkoxylated closo-dodecaborates [B12X11OR](2-) (X = Cl, Br; R = propyl, octyl, dodecyl) have been synthesized by halogenation of the known [B12H11OH](2-) anion followed by alkylation in the superbasic medium DMSO/KOH. The obtained sodium salts were transformed by simple metathesis reactions in aqueous solution to the tetrabutylammonium ([NBu4](+)) and 1-hexyl-3-methylimidazolium...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Chemical communications

دوره 49 21  شماره 

صفحات  -

تاریخ انتشار 2013