1,4-Bis(pyrimidin-2-ylsulfanyl)butane
نویسندگان
چکیده
The -SCH(2)CH(2)CH(2)CH(2)S- portion of the title compound, C(12)H(14)N(2)S(2), adopts an extended zigzag conformation. The angles at the tetra-hedral carbon atoms are marginally increased [113.63 (12)° and 111.38 (17)° for S-C-C and C-C-C respectively] from the idealized tetra-hedral angle. The mol-ecule lies on an inversion center located at the mid-point of the butyl chain. In the crystal, there is a π-π stacking inter-action between inversion-related pyrimidine rings with mean inter-planar spacing of 3.494 (2) Å.
منابع مشابه
1,4-bis(triphenyl phosphonium)butane peroxodisulfate: conversion of alkyl benzenes to carbonyl compounds
1,4-bis(triphenyl phosphonium)butane peroxodisulfate(BTPPBPDS) were synthesized by treating 1,4-bis(triphenyl phosphonium)butane dibromide and potassium peroxydisulfate in aqueous solution.This was used mild and efficient reagent for oxidation of alkyl benzenes to their corresponding carbonyl compounds in very good to high yields.
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