Catalytic micropumps: microscopic convective fluid flow and pattern formation.
نویسندگان
چکیده
As innovations continue to be made in the fields of microfluidics and the colloidal assembly, new strategies for moving particles and fluids may be needed. Heterogeneous catalysis provides means of locally converting the stored chemical energy of fuels to mechanical energy. We report an ambient temperature stationary "pump" that generates a proton concentration gradient through the bipolar electrochemical decomposition of hydrogen peroxide on patterned silver-gold surfaces. The resulting electric field drives convective fluid flow and pattern formation of colloidal tracer particles at the microscopic level by a combination of electroosmotic and electrophoretic forces.
منابع مشابه
CFD Simulation of Dry and Wet Pressure Drops and Flow Pattern in Catalytic Structured Packings
Type of packings and characteristics of their geometry can affect the flow behavior in the reactive distillation columns. KATAPAK SP is one the newest modular catalytic structured packings (MCSP) that has been used in the reactive distillation columns, recently. However, there is not any study on the hydrodynamics of this packing by using computational fluid dynamics. In the present work, a 3D ...
متن کاملSolutal and thermal buoyancy effects in self-powered phosphatase micropumps.
Immobilized enzymes generate net fluid flow when exposed to specific reagents in solution. Thus, they function as self-powered platforms that combine sensing and on-demand fluid pumping. To uncover the mechanism of pumping, we examine the effects of solutal and thermal buoyancy on the behavior of phosphatase-based micropumps, using a series of reactants with known thermodynamic and kinetic para...
متن کاملImaging the proton concentration and mapping the spatial distribution of the electric field of catalytic micropumps.
Catalytic engines can use hydrogen peroxide as a chemical fuel in order to drive motion at the microscale. The chemo-mechanical actuation is a complex mechanism based on the interrelation between catalytic reactions and electro-hydrodynamics phenomena. We studied catalytic micropumps using fluorescence confocal microscopy to image the concentration of protons in the liquid. In addition, we meas...
متن کاملThree-Dimensional Boundary Layer Flow and Heat Transfer of a Dusty Fluid Towards a Stretching Sheet with Convective Boundary Conditions
The steady three-dimensional boundary layer flow and heat transfer of a dusty fluid towards a stretching sheet with convective boundary conditions is investigated by using similarity solution approach. The free stream along z-direction impinges on the stretching sheet to produce a flow with different velocity components. The governing equations are reduced into ordinary differential equations b...
متن کاملUnsteady convective flow for MHD powell-eyring fluid over inclined permeable surface
The current article has investigated unsteady convective flow for MHD non-Newtonian Powell-Eyring fluid embedded porous medium over inclined permeable stretching sheet. We have pondered the thermophoresis parameter, chemical reaction, variable thermal conductivity, Brownian motion, variable heat source and variable thermal radiation in temperature and concentration profiles. Using similar trans...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 127 49 شماره
صفحات -
تاریخ انتشار 2005