Bis[N-(8-quinolyl)pyridine-2-carboxamidato-κ3 N,N′,N′′]manganese(III) perchlorate monohydrate
نویسندگان
چکیده
The Mn(III) ion in the title complex, [Mn(C(15)H(10)N(3)O)(2)]ClO(4)·H(2)O, is coordinated meridionally by six N atoms from two tridentate N-(8-quinol-yl)pyridine-2-carboxamidate ligands, yielding a distorted octa-hedral coordination geometry. The two ligands are nearly planar and their mean planes are almost perpendicular, with a dihedral angle of 86.7 (2)°.
منابع مشابه
Bis[N-(pyridin-2-ylcarbonyl)pyridine-2-carboximidato-κ3 N,N′,N′′]iron(III) tris(cyanido-κC)[N-(pyridin-2-ylcarbonyl)pyridine-2-carboximidato-κ3 N,N′,N′′]ferrate(III) monohydrate
In the title compound, [Fe(C(12)H(8)N(3)O(2))(2)][Fe(C(12)H(8)N(3)O(2))(CN)(3)]·H(2)O, the Fe(3+) ions in the cation and anion each lie in a slightly distorted octa-hedral coordination environment. The solvent water mol-ecule is disordered over three positions with occupancies of 0.401 (7), 0.322 (7) and 0.277 (6). The water content was confirmed by thermogravimetric data.
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