A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor.
نویسندگان
چکیده
A 1,3-dipolar cycloaddition reaction taking place quantitatively between propiolic acid "guests" and azide functions previously attached to binding sites within the cavity of a {Mo(132)}-type Keplerate reproducibly gives a 2 : 1 ratio of 1,4- and 1,5-triazoles.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 41 33 شماره
صفحات -
تاریخ انتشار 2012