Bis[1-(2-hydroxyethyl)-2-methyl-5-nitro-1H-imidazole-κN 3]silver(I) nitrate
نویسندگان
چکیده
In the title compound, [Ag(C(6)H(9)N(3)O(3))(2)]NO(3), the Ag atom is bicoordinated in a distorted linear configuration by two 1-(2-hydroxy-ethyl)-2-methyl-5-nitro-imidazole ligands through one of the N atoms. The dihedral angle between the two imidazole rings is 16.1 (2)°. The O atoms of the nitrate anion are disordered over two positions; the site occupancy factors are 0.8 and 0.2. The ions are -connected by C-H⋯O inter-actions, while two weak intra-molecular C-H⋯O inter-actions producing an S(6) ring motif are observed. The nitrate anion is linked to the hydroxyl groups of two neighbouring cations by O-H⋯O hydrogen bonds. The ions are packed into infinite chains along the [100] direction.
منابع مشابه
Bis(2-methyl-1H-imidazole-κN 3)silver(I) nitrate dihydrate
The Ag(I) atom in the salt, [Ag(C(4)H(6)N(2))(2)]NO(3)·2H(2)O, shows a nearly linear coordination [N-Ag-N = 178.26 (7)°]. The cation, anion and water mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds into a layer motif extending parallel to (101).
متن کاملBis(2-phenyl-1H-imidazole-κN 3)silver(I) nitrate
The asymmetric unit of the title compound, [Ag(C(9)H(8)N(2))(2)]NO(3), contains one complete [Ag(C(9)H(8)N(2))(2)](+) cation and two half-cations (with the other halves generated through inversion) and two NO(3) (-) anions. Each Ag(I) ion shows a linear AgN(2) coordination. The ions are linked by N-H⋯O hydrogen bonds.
متن کاملCrystal structure of bis[1-(2-hydroxyethyl)-2-methyl-5-nitro-1H-imidazole-κN 3]silver(I) tetrafluoridoborate methanol monosolvate
1-(2-Hy-droxy-eth-yl)-2-methyl-5-nitro-1H-imidazole (metronidazole, MET) is a medication that is used to treat infections by a variety of anaerobic organisms, but there are relatively few reports of the structures of metal compounds that exhibit coordination of metronidazole. We have demonstrated that MET reacts with AgBF4 to give [Ag(MET)2]BF4·CH3OH, in which the Ag(I) cation is coordinated by...
متن کاملcatena-Poly[[bis(1-methyl-1H-imidazole-κN 3)zinc]-μ-3-nitrophthalato-κ2 O 1:O2]
In the title complex, [Zn(C(8)H(3)NO(6))(C(4)H(6)N(2))(2)](n), the carboxyl-ate groups of the 3-nitro-phthalate dianion ligand coordinate the Zn(II) ion in a bis-monodentate mode. The Zn(II) ion shows distorted tetra-hedral coordination as it is bonded to two O atoms from the carboxyl-ate groups of symmetry-related 3-nitro-phthalate anions and two N atoms of two independent 1-methyl-imidazole m...
متن کاملBis(4-methyl-3,5-diphenyl-1H-pyrazole-κN 2)silver(I) nitrate
In the title complex, [Ag(C(16)H(14)N(2))(2)]NO(3), the geometry around the Ag(I) ion is T-shaped with two short Ag-N bonds to the pyrazole ligand and one long Ag-O bond to the nitrate anion. The crystal structure is stabilized by inter-molecular N-H⋯O, C-H⋯O and C-H⋯π inter-actions.
متن کامل