Thermodynamic consistency tests for solid-liquid equilibria
نویسندگان
چکیده
منابع مشابه
Thermodynamic Properties and Phase Equilibria for Liquid Fluorine Using GMA Equation of State
Thermophysical properties of fluorine are interesting because of its applications in different areas of technologyand industry. The computations of thermodynamic properties were performed with the GMA equation of stateunder critical conditions. The present work reports calculations of density, volumetric, and thermodynamicproperties of liquid fluorine on extended ranges of pressure and temperat...
متن کاملthermodynamic properties and phase equilibria for liquid fluorine using gma equation of state
thermophysical properties of fluorine are interesting because of its applications in different areas of technologyand industry. the computations of thermodynamic properties were performed with the gma equation of stateunder critical conditions. the present work reports calculations of density, volumetric, and thermodynamicproperties of liquid fluorine on extended ranges of pressure and temperat...
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A Monte Carlo simulation study is made of the phase diagram of the restricted primitive model and of the solid± liquid and solid± solid phase coexistence curves in particular. At low temperatures, there is liquid± bcc coexistence and with increasing density there is bcc± fcc coexistence. These coexistence curves end in a triple point (liquid± bcc ± fcc) above which only liquid± fcc coexistence ...
متن کاملMolecular Simulation of Three-body Interactions for Vapor-liquid and Solid-liquid Phase Equilibria
The phase behavior of both pure systems and binary mixtures has been widely studied by molecular simulation [1], using techniques such as the Gibbs ensemble [2], Gibbs-Duhem [3] or histogram reweighing [4] algorithms. The common aim of many of these investigations is to accurately predict the phase diagram using effective intermolecular potentials, most notable the Lennard-Jones potential. In c...
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The solid–liquid phase diagrams of two binary mixtures of saturated fatty acids, formed by caprylic acid (C8:0) + myristic acid (C14:0) and lauric acid (C12:0) + myristic acid (C14:0), were measured using high pressure microscopy in the range of 0.1–90 MPa. It is shown that unlike for other long chain alkyl compounds such as alkanes the phase diagrams are only slightly affected by the pressure,...
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ژورنال
عنوان ژورنال: AIChE Journal
سال: 1965
ISSN: 0001-1541,1547-5905
DOI: 10.1002/aic.690110507