Synthesis and X-ray Diffraction Study of thiosemicarbazone Palladacycles with dppm
نویسندگان
چکیده
Cyclometallated compounds have been extensively studied, in particular those with palladium and platinum. This is because of their possible applications medicinal chemistry, as anticancer or antimicrobial agents; some cases, similar results cisplatin, carboplatin oxaliplatin. What also remarkable use homogeneous catalysts, for example, cross coupling reactions such Suzuki–Miyaura Mizoroki–Heck. Herein, we report the synthesis different thiosemicarbazone ligands, which will be reacted a platinum salt, to give corresponding cyclometallated compounds; addition, reactivity bis(diphenylphosphino)methane (dppm) studied. Characterization has carried out by elemental analysis, IR spectroscopy, 1H 31P NMR spectroscopy. Additionally, 1c studied X-ray diffraction.
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ژورنال
عنوان ژورنال: Proceedings
سال: 2021
ISSN: ['0890-1740']
DOI: https://doi.org/10.3390/proceedings2020062013