Soy-Based Polyols and Polyurethanes

Structure-property studies of thermoplastic and thermosetting polyurethanes using palm and soya oils-based polyols.

Palm and soya oils were converted to monoglycerides via transesterification of triglycerides with glycerol by one step process to produce renewable polyols. Thermoplastic polyurethanes (TPPUs) were prepared from the reaction of the monoglycerides which act as polyol with 4,4'-methylenediphenyldiisocyanate (MDI) whereas, thermosetting polyurethanes (TSPUs) were prepared from the reaction of glyc...

Oleic and Undecylenic Acids as Renewable Feedstocks in the Synthesis of Polyols and Polyurethanes

Nowadays, the utilization of raw materials derived from renewable feedstock is in the spotlight of the chemical industry, as vegetable oils are one of the most important platform chemicals due to their universal availability, inherent biodegradability and low price. Taking into account that polyurethanes are one of the most important industrial products exhibiting versatile properties suitable ...

One-Pot Conversion of Epoxidized Soybean Oil (ESO) into Soy-Based Polyurethanes by MoCl₂O₂ Catalysis.

An innovative and eco-friendly one-pot synthesis of bio-based polyurethanes is proposed via the epoxy-ring opening of epoxidized soybean oil (ESO) with methanol, followed by the reaction of methoxy bio-polyols intermediates with 2,6-tolyl-diisocyanate (TDI). Both synthetic steps, methanolysis and polyurethane linkage formation, are promoted by a unique catalyst, molybdenum(VI) dichloride dioxid...

Formulating polyurethanes using case based reasoning

Seed Oil Based Polyurethanes: An Insight

Seed oils [SO] are cost‐effective, eco‐friendly and biodegradable in nature. They bear functional groups such as carboxyls, esters, double bonds, active methylenes, hydroxyls, oxirane rings and others, amenable to several derivatization reactions. Their abundant availability, non‐toxicity and rich chemistry has established SO as focal point of polymer production, e.g., production of polyesters,...