Photovoltaic-driven organic electrosynthesis and efforts toward more sustainable oxidation reactions
نویسندگان
چکیده
منابع مشابه
Photovoltaic-driven organic electrosynthesis and efforts toward more sustainable oxidation reactions
The combination of visible light, photovoltaics, and electrochemistry provides a convenient, inexpensive platform for conducting a wide variety of sustainable oxidation reactions. The approach presented in this article is compatible with both direct and indirect oxidation reactions, avoids the need for a stoichiometric oxidant, and leads to hydrogen gas as the only byproduct from the correspond...
متن کاملEfforts toward a More Consistent and Interoperable Sequence Ontology
The Sequence Ontology (SO), a member of the Open Biomedical On-‐ tologies (OBOs) library, was developed with the goals of standardizing the vocabulary and semantics of biological-‐sequence annotation with the goal of increased interoperability for software developers and users ...
متن کاملElectrosynthesis: A New Frontier in Aerobic Oxidation?
The formation of alcohols and carbonyl derivatives via oxidation of the corresponding Csp–H bonds is crucial to the chemical community. Historically chemists have relied for these transformations on the use of organic or inorganic oxidants, which are often toxic and produce stoichiometric amounts of harmful waste. As we strive for a more sustainable fine chemicals synthesis, for which typically...
متن کاملFluctuating Efforts and Sustainable Cooperation
We show that when individuals confronted with a social dilemma contribute to the common good with an effort that fluctuates in time, they can make the group generate an average utility that actually decreases in time. This paradoxical behavior takes place in spite of the fact that typically individuals are found to be contributing at any given time. This novel phenomenon, which we verified in a...
متن کاملReductive electrosynthesis of crystalline metal-organic frameworks.
Electroreduction of oxoanions affords hydroxide equivalents that induce selective deposition of crystalline metal-organic frameworks (MOFs) on conductive surfaces. The method is illustrated by cathodic electrodeposition of Zn(4)O(BDC)(3) (MOF-5; BDC = 1,4-benzenedicarboxylate), which is deposited at room temperature in only 15 min under cathodic potential. Although many crystalline phases are k...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Beilstein Journal of Organic Chemistry
سال: 2015
ISSN: 1860-5397
DOI: 10.3762/bjoc.11.32