Nitrile sulfides. Part 12.1,2 Generation of nitrile sulfides from 1,4,2-dithiazol-5-ones
نویسندگان
چکیده
منابع مشابه
synthesis of sulfides from alcohols and thiols in solvent-freeconditions and deoxygenation of sulfoxides
کاتالیست یک سنتز جدید برای تیواترها توصیف شده است. واکنش الکل ها با آریل، هتروآریل و آلکیل تیو ل ها درحضور 1،3،5- تری آزو- 2،4،6- تری فسفرین-2،2،4،4،6،6 هگزاکلراید ((tapc به عنوان یک کاتالیست موُثر، بازده های خوب تا عالی از تیواترها را حاصل می کند. علاوه براین، واکنش تحت شرایط بدون فلز و بدون حلال پیش می رود، بنابراین یک مکمل جالب برای روش های شناخته شده سنتز تیواترها ارائه می دهد. یک مکانیسم ا...
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Nitriles are a diverse group of organic compounds with –C≡N as functional group. Most nitriles are slightly cytotoxic but some cause severe toxic effects. More than 120 naturally occurring nitriles without considering cyanogenic glycosides are present in terrestrial and marine habitats, especially in plant components such as almonds or other fruit pits. The most common group of naturally occurr...
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A b-diketiminato n-butylmagnesium complex is presented as a selective precatalyst for the reductive hydroboration of organic nitriles with pinacolborane (HBpin). Stoichiometric reactivity studies indicate that catalytic turnover ensues through the generation of magnesium aldimido, aldimidoborate and borylamido intermediates, which are formed in a sequence of intramolecular nitrile insertion and...
متن کاملComparative metabolism of geranyl nitrile and citronellyl nitrile in mouse, rat, and human hepatocytes.
Geranyl nitrile (GN) and citronellyl nitrile (CN) are fragrance components used in consumer and personal care products. Differences in the clastogenicity of these two terpenes are postulated to result from differential biotransformation, presumably involving the conjugated nitrile moiety. The metabolic clearance and biotransformation of GN and CN were compared in primary hepatocytes from mice, ...
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ژورنال
عنوان ژورنال: Arkivoc
سال: 2002
ISSN: 1551-7012
DOI: 10.3998/ark.5550190.0003.313