Kinetics and mechanism of oxidation of aliphatic primary alcohols by quinolinium bromochromate
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چکیده
منابع مشابه
Quinolinium Dichromate Oxidation of Aliphatic Aldehydes: A Kinetic Study
Kinetic data on the rates of quinolinium dichromate oxidation of a series of aliphatic aldehydes have been determined and discussed with reference to aldehyde hydration equilibria. Kinetic results support a pathway proceeding via a rate-determining oxidative decomposition of a chromate ester of an aldehyde hydrate. A cyclic transition state is suggested; being a Hückel-type system (4n + 2), thi...
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ژورنال
عنوان ژورنال: Journal of Chemical Sciences
سال: 2003
ISSN: 0253-4134,0973-7103
DOI: 10.1007/bf02899321