Iron(I)‐Based Carbonyl Complexes with Bridging Thiolate Ligands as Light‐Triggered CO Releasing Molecules (photoCORMs)
نویسندگان
چکیده
منابع مشابه
Iron indenyl carbonyl compounds: CO-releasing molecules.
New CO-releasing molecules, CO-RMs, based on indenyl iron carbonyls have been identified. Half-lives for carbon monoxide (CO) release, (1)H NMR, (13)C NMR, IR, mass spectra, elemental analysis and biological data have been determined for the compounds. Limited correlations have been made between half-lives and ΔG(‡) for CO release and spectroscopic parameters, ν(CO) and δ((13)CO). X-ray structu...
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Novel organic photoCORMs based on micelle-encapsulated unsaturated cyclic α-diketones were designed and synthesized. These photoCORMs can be activated by visible light, have potentially low toxicity, allow the delivery of carbon monoxide to be monitored by fluorescence imaging techniques, and thus are useful tools for the study of the biological function of CO.
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Two manganese(i) carbonyl complexes derived from α,α'-diimine ligands with extended conjugated framework namely [MnBr(CO)3(BIAN)] () and [MnBr(CO)3(MIAN)] (), have been synthesized and structurally characterized. Unlike the previously reported photoactive CO-releasing molecules (photoCORMs), these two complexes exhibit unusually high sensitivity toward low power (0.3-10 mW) visible light (λ ≥ 5...
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Mn(I) carbonyl terpyridyl complexes have been synthesized and characterized. The tricarbonyl derivative exhibits interesting behaviors for controlled CO-release by both thermal and photosynthetic pathways.
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Reprint requests to Dr. B. Kersting. E-mail: [email protected] Z. Naturforsch. 55 b, 1179-1187 (2000); received August 17, 2000 Cobalt Complexes, Amine-Thiolate Ligands, Sulfinate Complexes The reactivity of Co111 amine-thiolate complexes with terminal and bridging thiolate func tions towards oxidizing agents has been investigated. The mononuclear Co N3S3 complex [Coni(L1)] (2)...
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ژورنال
عنوان ژورنال: Zeitschrift für anorganische und allgemeine Chemie
سال: 2019
ISSN: 0044-2313,1521-3749
DOI: 10.1002/zaac.201900162