Effect of post annealing thermal heating on Cu2ZnSnS4 solar cells processed by sputtering technique

نویسندگان

چکیده

• Thermal annealing of Cu 2 ZnSnS 4 solar cell in air improved the characteristics. The band gap decreased with thermal air. Cd diffusion was observed from CdS to . Increase external quantum efficiency hot-plate annealing. In this work, a detailed study effect treatment (hot plate) on Mo/CZTS/CdS/i-ZnO/ITO carried out, which promotes contained window layer towards absorber CZTS. out at temperatures ranging 100 °C 400 and times varying 3 15 min atmosphere. CZTS grown deposits metallic precursors (Cu/Sn/Cu/Zn) by sputtering two ramps: 200° C for 45 an argon flow 1 mbar 550 5 bar atmosphere S + Sn. For complete cells hotplate 280 6 increase 2.7% 5.2% conversion compared without treatment. 1.56 1.43 eV Jsc increased 12.0 mA/cm 15.4

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ژورنال

عنوان ژورنال: Solar Energy

سال: 2022

ISSN: ['0375-9865', '1471-1257', '0038-092X']

DOI: https://doi.org/10.1016/j.solener.2022.04.002