Controlling Achiral and Chiral Properties with an Electric Field: A Next-Generation QTAIM Interpretation

نویسندگان

چکیده

We used the recently introduced stress tensor trajectory Uσ space construction within framework of next-generation quantum theory atoms in molecules (NG-QTAIM) for a chirality investigation alanine when subjected to non-structurally distorting electric field. The resultant sliding axial-bond critical point (BCP) responded significantly, up twice as much, presence applied field comparison its absence. bond flexing, measure strain, was always lower by factor four field, depending on direction and magnitude. An achiral character 7% found entirely absent lowest value Future applications, including molecular devices using left right circularly polarized laser pulses, are briefly discussed.

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ژورنال

عنوان ژورنال: Symmetry

سال: 2022

ISSN: ['0865-4824', '2226-1877']

DOI: https://doi.org/10.3390/sym14102075