Cocrystals of Barbituric Acid with Alkali Metal Halides

Complex metal halides in fused alkali nitrates

The results of this investigation have provided additional information by chemical methods of the extent of association in fused salts. Association effects observed in solubility and rate studies in fused alkali nitrate are shown to be consistent with the assumption that complex ions such as those existing in aqueous solutions are formed between metal ions and halide ions. In addition, the rate...

Alkali metal actinide complex halides : thermochemical and structural considerations

— The present status of our information on the thermodynamics of the actinide halogeno-complexes with alkali metal ions is reviewed, with special emphasis on chloroand bromo-derivatives. Where enough thermodynamic and structural data are available, attempts are made to deduce the evolution of the energetics of the actinide-halogen bonds along a series of isomorphous or analogous compounds. The ...

Suppressing Nucleation in Metal-Organic Chemical Vapor Deposition of MoS2 Monolayers by Alkali Metal Halides.

Toward the large-area deposition of MoS2 layers, we employ metal-organic precursors of Mo and S for a facile and reproducible van der Waals epitaxy on c-plane sapphire. Exposing c-sapphire substrates to alkali metal halide salts such as KI or NaCl together with the Mo precursor prior to the start of the growth process results in increasing the lateral dimensions of single crystalline domains by...

Frenkel Defects in Alkali Halides

Reactions of Amino-imino-boranes with Transition Metal Halides and Substituted Transition Metal Halides

The aminoiminoborane tmp-B=NCMe3 (1) adds to TiBr4 or ZrCL in a 1:1 ratio while PdCh adds 1 in a 1:2 ratio. In these new compounds the NBN unit is almost linear and the configuration corresponds to an allene. On the other hand 1 and Ti(OR)4 compounds and Ti(NMe2)4 give N metallated diaminoboranes tmp-B(X)-NCMe3EX3 (X = OR, NMe2). Mixed compounds Ti(OR)3_„X„ lead to diaminoboranes with BOR group...