Charge Carrier Dynamics upon Sub-bandgap Excitation in Methylammonium Lead Iodide Thin Films: Effects of Urbach Tail, Deep Defects, and Two-Photon Absorption
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چکیده
منابع مشابه
Temperature Dependent Charge Carrier Dynamics in Formamidinium Lead Iodide Perovskite
The fundamental opto-electronic properties of organic-inorganic hybrid perovskites are strongly affected by their structural parameters. These parameters are particularly critical in formamidinium lead iodide (FAPbI3), in which its large structural disorder leads to a non-perovskite yellow phase that hinders its photovoltaic performance. A clear understanding of how the structural parameters af...
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We reveal substantial luminescence yield heterogeneity among individual subdiffraction grains of high-performing methylammonium lead halide perovskite films by using high-resolution cathodoluminescence microscopy. Using considerably lower accelerating voltages than is conventional in scanning electron microscopy, we image the electron beam-induced luminescence of the films and statistically cha...
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The small exciton binding energy of perovskite suggests that the long-lived photoluminescence and slow recovery of the ground state bleaching of the tetragonal phase at room temperature results primarily from the decay of free charges rather than the decay of the initially created excitons. Here we demonstrate the ground state bleaching recovery of the orthorhombic phase of methylammonium lead ...
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Observations on Surface Microtopography of gel grown PbI crystals and thin films of gel 2 grown PbI crystals are reported. Initiation of 2 growth layers, interlacing pattern, dendritic growth, symmetry and asymmetry hexagonal arms and natural triangular etch pits were seen. The surface topography, of gel grown PbI crystals and 2 of thin films of gel grown PbI have been related to 2 the growth ...
متن کاملInterfacial Charge Transfer Anisotropy in Polycrystalline Lead Iodide Perovskite Films.
Solar cells based on organic-inorganic lead iodide perovskite (CH3NH3PbI3) exhibit remarkably high power conversion efficiency (PCE). One of the key issues in solution-processed films is that often the polycrystalline domain orientation is not well-defined, which makes it difficult to predict energy alignment and charge transfer efficiency. Here we combine ab initio calculations and photoelectr...
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ژورنال
عنوان ژورنال: ACS Energy Letters
سال: 2020
ISSN: 2380-8195,2380-8195
DOI: 10.1021/acsenergylett.0c02067