A study of mono-, di- and tri-tosylated amines: An unexpected sulfonamide
نویسندگان
چکیده
2-Aminobenzylaniline was ditosylated and gave an unexpected product N,N-ditosylamino-2-benzylaminobenzene in which the primary amine had ditosylated, benzylamine unreacted. The benzylamine, although more electron rich, is sterically crowded less nucleophilic than this system. Sterically tosylamides were prepared by reacting o-phenylenediamine, p-phenylenediamine 1,8-diaminonaphthalene with tosyl chloride.
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ژورنال
عنوان ژورنال: Journal of chemical research
سال: 2023
ISSN: ['1747-5198', '2047-6507']
DOI: https://doi.org/10.1177/17475198231194866