[3-(Iodoacetamido)propyl]triphenylphosphonium tetraphenylborate

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N-(Diphenylselenio)diphenylsulfimidium tetraphenylborate.

The title compound, C24H20NSSe+.C24H20B-, exhibits disorder (S/Se scrambling) of the chalcogen sites within the S-N-Se triad. Similar disorder was observed in the bromide salt [Aucott, Bailey, Elsegood, Gilby, Holmes, Kelly, Papageorgiou & Pedron-Haba (2004). New J. Chem. pp. 959-966]. The S-N and Se-N bond lengths are 1.6735 (15) and 1.8045 (14) A, respectively. Whereas the chalcogens in the b...

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Membrane formation by preferential solvation of ions in mixture of water, 3-methylpyridine, and sodium tetraphenylborate.

The structure and dynamics of a ternary system composed of deuterium oxide (D2O), 3-methylpyridine (3MP), and sodium tetraphenylborate (NaBPh4) are investigated by means of small-angle neutron scattering (SANS) and neutron spin echo (NSE) techniques. In the SANS experiments, a structural phase transition is confirmed between a disordered-phase and an ordered-lamellar-phase upon variation of the...

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Structure and Molecular Motions in Rubidium Tetraphenylborate

By X-ray diffraction it was found that at 293 K the crystals of rubidium tetraphenylborate are tetragonal, space group I4̄2m, a = b = 11.212(2) Å, c = 8.098(2) Å, with 2 molecules of Rb[C24H20B] # in the unit cell. The molecular reorientations as functions of temperature were studied by H NMR. Two types of motions were detected: an anisotropic reorientation of the tetraphenylborate anions about ...

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2-Dimethylamino-1-(2-ethoxy-2-oxo­ethyl)-3-methyl-3,4,5,6-tetrahydro­pyrimidin-1-ium tetraphenylborate

Isolated guanidinium ions and tetra-phenyl-borate ions are present in the crystal structure of the title compound, C(11)H(22)N(3)O(2) (+)·C(24)H(20)B(-). In the guanidinium ion, the dihedral angle between the N/C/N and C/C/C planes being 49.9 (1)°. The six-membered ring exhibits a half-chair conformation. The C-N bond lengths in the cation range between 1.3335 (16) and 1.3552 (16) Å, indicating...

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The presence of tetraphenylborate (TPB, 10 -3 M to 10 -4 M) in goldfish brain articulate preparations during a 5-15 min incubation with Y-~~P-ATP or y3f; P ATP results in marked stimulation of labeling of phosphatidate and a decrease in labeling of phosphatidyl inositol phosphate. Incorporation into phosphatidyl inositol diphosphate, a minor labeled phospholipid, is also depressed by TPB. We su...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s160053681000142x